Skip Main Navigation Links Jump to Footer
Journal of the American Chemical SocietyVolume 127, Issue 8, 2 March 2005, Pages 2533-2537

Nanoscale vibrational analysis of single-walled carbon nanotubes(Article)

  • aInstitute of Optics, University of Rochester, Rochester, NY 14627, United States
  • bPhysikalische Chemie, Universitat Siegen, 57068 Siegen, Germany
  • cDepartment of Physics, Harvard University, Cambridge, MA 02138, United States

Abstract

We use near-field Raman imaging and spectroscopy to study localized vibrational modes along individual, single-walled carbon nanotubes (SWNTs) with a spatial resolution of 10-20 nm. Our approach relies on the enhanced field near a laser-irradiated gold tip which acts as the Raman excitation source. We find that for arc-discharge SWNTs, both the radial breathing mode (RBM) and intermediate frequency mode (IFM) are highly localized. We attribute such localization to local changes in the tube structure (n, m). In comparison, we observe no such localization of the Raman active modes in SWNTs grown by chemical vapor deposition (CVD). The direct comparison between arc-discharge and CVD-grown tubes allows us to rule out any artifacts induced by the supporting substrate. © 2005 American Chemical Society.

Indexed keywords

Engineering controlled terms:Chemical vapor depositionGoldGrowth kineticsLaser beam effectsMolecular vibrationsRaman spectroscopySubstrates
Engineering uncontrolled terms:Intermediate frequency modes (IFM)Raman imagingSingle-walled carbon nanotubes (SWNT)Spatial resolution
Engineering main heading:Carbon nanotubes
EMTREE drug terms:carbon nanotubegold
EMTREE medical terms:articleartifact reductionchemical vapor depositionimage analysisimage reconstructionlasermechanical probeRaman spectrometryvaporvibration

Chemicals and CAS Registry Numbers:

gold, 7440-57-5

  • ISSN: 00027863
  • CODEN: JACSA
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1021/ja045190i
  • Document Type: Article

  Novotny, L.; Institute of Optics, University of Rochester, United States;
© Copyright 2008 Elsevier B.V., All rights reserved.

Cited by 170 documents

Li, Z.-Y.
Mesoscopic and Microscopic Strategies for Engineering Plasmon-Enhanced Raman Scattering
(2018) Advanced Optical Materials
Xie, Z. , Duan, S. , Tian, G.
Theoretical modeling of tip-enhanced resonance Raman images of switchable azobenzene molecules on Au(111)
(2018) Nanoscale
Li, Z. , Gong, Q.
Scanning near-field optical microscopy
(2017) Advances in Nanophotonics
View details of all 170 citations