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Journal of Chemical PhysicsVolume 122, Issue 18, 8 May 2005, Article number 184716

Plasmon resonances on metal tips: Understanding tip-enhanced Raman scattering(Article)

  • Department of Physics, King's College London, Strand, London WC2R 2LS, United Kingdom

Abstract

Calculations of the electric-field enhancements in the vicinity of an illuminated silver tip, modeled using a Drude dielectric response, have been performed using the finite difference time domain method. Tip-induced field enhancements, of application in "apertureless" Raman scanning near-field optical microscopy (SNOM), result from the resonant excitation of plasmons on the metal tip. The sharpness of the plasmon resonance spectrum and the highly localized nature of these modes impose conditions to better exploit tip plasmons in tip-enhanced apertureless SNOM. The effect of tip-to-substrate separation and polarization on the resolution and enhancement are analyzed, with emphasis on the different field components parallel and perpendicular to the substrate. © 2005 American Institute of Physics.

Indexed keywords

Engineering uncontrolled termsDrude dielectric responseGlass substratePlasmon resonancesRaman scattering near-field optical microscopy (SNOM)
Engineering controlled terms:Dielectric materialsElectric fieldsFinite difference methodGlassLight polarizationMathematical modelsMicroscopic examinationRaman scatteringScanningSilverSpectrum analysisSubstratesTime domain analysis
Engineering main heading:Surface plasmon resonance

Funding details

Funding numberFunding sponsorAcronymFunding opportunities
Engineering and Physical Sciences Research CouncilEPSRCSee opportunities by EPSRC
  • 1

    We would like to thank Robert Milner for his initial development of the code. We are grateful to the EPSRC for their support.

  • ISSN: 00219606
  • CODEN: JCPSA
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1063/1.1896356
  • Document Type: Article

  Demming, A.L.; Department of Physics, King's College London, United Kingdom
© Copyright 2012 Elsevier B.V., All rights reserved.

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