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Physical Chemistry Chemical PhysicsVolume 8, Issue 1, 2006, Pages 165-170

Aspect ratio dependence on surface enhanced Raman scattering using silver and gold nanorod substrates(Article)

  • aUniversity of South Carolina, Department of Chemistry and Biochemistry, Columbia, SC 29208, United States
  • bPresbyterian College, Department of Chemistry, 503 South Broad St., Clinton, SC 29325, United States
  • cInstitute of Bioengineering and Nanotechnology, Singapore Science Park II, 51 Science Park Rd., Singapore, 117586, Singapore

Abstract

Silver and gold nanorods with aspect ratios from 1 to 16 have been used as substrates for surface enhanced Raman spectroscopy (SERS) in colloidal solution. The nanorod aspect ratio is varied to give different degrees of overlap between the nanorod longitudinal plasmon band and excitation source in order to determine its effect on overall surface enhancement. Results suggest that enhancement factors are a factor of 10-102 greater for substrates that have plasmon band overlap with the excitation source than for substrates whose plasmon bands do not. © the Owner Societies 2006.

Indexed keywords

EMTREE drug terms:goldsilver
EMTREE medical terms:articlechemistrycolloidmethodologynanotechnologyparticle sizeRaman spectrometrysolution and solubilitysurface propertytransmission electron microscopy
MeSH:ColloidsGoldMicroscopy, Electron, TransmissionNanotechnologyParticle SizeSilverSolutionsSpectrum Analysis, RamanSurface Properties

Chemicals and CAS Registry Numbers:

gold, 7440-57-5; silver, 7440-22-4;

Colloids; Gold, 7440-57-5; Silver, 7440-22-4; Solutions

  • ISSN: 14639076
  • CODEN: PPCPF
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1039/b512573a
  • PubMed ID: 16482257
  • Document Type: Article

  Murphy, C.J.; University of South Carolina, Department of Chemistry and Biochemistry, United States;
© Copyright 2008 Elsevier B.V., All rights reserved. © MEDLINE® is the source for the MeSH terms of this document.

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