Skip Main Navigation Links Jump to Footer
Review of Scientific InstrumentsVolume 79, Issue 1, 2008, Article number 013706

Highly efficient tip-enhanced Raman spectroscopy and microscopy of strained silicon(Article)

  • aNanophotonics Laboratory, Institute of Physical and Chemical Research (RIKEN), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan
  • bCREST, Japan Science and Technology Agency, Kawaguchi, Saitama 332-0012, Japan
  • cDepartment of Precision Science and Technology and Applied Physics, Osaka University, Suita, Osaka 565-0871, Japan

Abstract

We present a versatile tip-enhanced Raman spectroscopy (TERS) system that permits efficient illumination and detection of optical properties in the visible range to obtain high signal-to-noise Raman signals from surfaces and interfaces of materials using an edge filter. The cutoff wavelength of the edge filter is tuned by changing the angle of incident beam to deliver high incident power and effectively collect scattered near-field signals for nanoscopic investigation in depolarized TERS configuration. The dynamic design of the instrument provides a unique combination of features that allows us to perform reflection or transmission mode TERS to cover both opaque and transparent samples. A detailed description of improvements of TERS was carried out on a thin strained silicon surface layer. The utilization of an edge filter for shorter collection time, specialized tip for higher field enhancement and for elimination of Raman signal from the tip, shorter wavelength, sample orientation relative to probing polarization, and depolarized configuration for higher contrast Raman signal is discussed. © 2008 American Institute of Physics.

Indexed keywords

Engineering controlled terms:Microscopic examinationOptical propertiesRaman spectroscopySignal to noise ratioWavelength
Engineering uncontrolled terms:Near field signalsStrained siliconTip enhanced Raman spectroscopy (TERS) systems
Engineering main heading:Silicon
EMTREE drug terms:silicon
EMTREE medical terms:articlechemistryequipmentequipment designinstrumentationmethodologynanotechnologyRaman spectrometryreproducibilityscanning probe microscopysensitivity and specificitysurface propertytransducer
MeSH:Equipment DesignEquipment Failure AnalysisMicroscopy, Scanning ProbeNanotechnologyReproducibility of ResultsSensitivity and SpecificitySiliconSpectrum Analysis, RamanSurface PropertiesTransducers

Chemicals and CAS Registry Numbers:

silicon, 7440-21-3;

Silicon, 7440-21-3

  • ISSN: 00346748
  • CODEN: RSINA
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1063/1.2832347
  • PubMed ID: 18248038
  • Document Type: Article

  Hayazawa, N.; Nanophotonics Laboratory, Institute of Physical and Chemical Research (RIKEN), 2-1 Hirosawa, Japan;
© Copyright 2008 Elsevier B.V., All rights reserved.

Cited by 25 documents

Jarzembski, A. , Shaskey, C. , Park, K.
Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials
(2018) Frontiers in Energy
Milekhin, A.G. , Rahaman, M. , Rodyakina, E.E.
Giant gap-plasmon tip-enhanced Raman scattering of MoS2monolayers on Au nanocluster arrays
(2018) Nanoscale
Berezin, S. , Aviv, Y. , Aviv, H.
Replacing a Century Old Technique-Modern Spectroscopy Can Supplant Gram Staining
(2017) Scientific Reports
View details of all 25 citations