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Journal of Raman SpectroscopyVolume 40, Issue 10, October 2009, Pages 1361-1370

Depolarization effects in tip-enhanced raman spectroscopy(Article)

  • aUniversité du Sud Toulon Var, IM2NP, Bâtiment R, BP 20132, F83957 La Garde Cedex, France
  • bCNRS, IM2NP (UMR 6242), France
  • cCNR Istituto per i Processi ChimicoFisici, sez, Messina, Salita Sperone Contrada Papardo, I98158 Messina, Italy
  • dLaboratoire de Chimie, Structure et Propriétés des Biomatériaux et d'Agents Thérapeutiques, UFR SMBH, Université Paris 13, 74 rue Marcel Cachin, 93017 Bobigny, France
  • eLPICM, Ecole Polytechnique, CNRS, 91128 Palaiseau, France

Abstract

Tip-enhanced Raman spectroscopy has proven to be a promising technique for stress/strain mapping of silicon-based semiconductor devices on the nanometer scale. Field enhancement factors of up to 104 have been reported and a spatial resolution down to 20 nm has been claimed through exploiting far-field suppression techniques based on an appropriate choice of the excitation/detection polarization states. In this paper, we show that depolarization of light due to scattering from the tip plays a key role in the selective enhancement of the one phonon optical mode peak at 520 cm-1 with respect to the two phononones. The spatial confinement of the selective enhancement has been studied by means of approach curves, and its dependence on the excitation wavelength and power further explored. Conclusions on the physical nature of the enhancement (depolarization- or plasmonic-based) are presented. © 2009 John Wiley & Sons, Ltd.

Author keywords

PolarizationSiliconTERS
  • ISSN: 03770486
  • CODEN: JRSPA
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1002/jrs.2424
  • Document Type: Article

  Merlen, A.; Université du Sud Toulon Var, IM2NP, Bâtiment R, BP 20132, France;
© Copyright 2009 Elsevier B.V., All rights reserved.

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