Skip to main content
Electrochimica ActaVolume 96, 30 April 2013, Pages 180-190

Modification of a Ti-Mo alloy surface via plasma electrolytic oxidation in a solution containing calcium and phosphorus(Article)(Open Access)

  • Simka, W.,
  • Krza̧kała, A.,
  • Korotin, D.M.,
  • Zhidkov, I.S.,
  • Kurmaev, E.Z.,
  • Cholakh, S.O.,
  • Kuna, K.,
  • Dercz, G.,
  • Michalska, J.,
  • Suchanek, K.,
  • Gorewoda, T.
  • View Correspondence (jump link)
  Save all to author list
  • aFaculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice, Poland
  • bInstitute of Metal Physics, Russian Academy of Sciences-Ural Division, S. Kovalevskoi Street 18, 620990 Yekaterinburg, Russian Federation
  • cUral Federal University, Mira Street 9, 620002 Yekaterinburg, Russian Federation
  • dInstitute of Materials Science, University of Silesia, Bankowa Street 12, 40-007 Katowice, Poland
  • eFaculty of Materials Science and Metallurgy, Silesian University of Technology, Krasińskiego Street 8, 40-019 Katowice, Poland
  • fHenryk Niewodniczanski Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow, Poland
  • gInstitute of Non Ferrous Metals, Sowińskiego Street 5, 44-100 Gliwice, Poland

Abstract

Investigations into the surface modification of a Ti-15Mo alloy via plasma electrolytic oxidation are reported. The oxidation process was conducted in a solution containing Ca(H2PO2)2, H 3PO4, or (HCOO)2Ca. Anodisation was performed at voltages in the range of 100-400 V. The morphology of the sample surface did not change during alloy oxidation at lower voltages. Higher voltages led to the incorporation of calcium and phosphorus or of calcium only into the formed oxide layer and to significant modification of the surface morphology. Based on the SEM and EDX analysis results, a set of samples was selected for further investigations. To study the surface of the Ti-Mo alloy after anodic oxidation, we used scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), thin-layer X-ray diffraction (TL-XRD), and X-ray photoelectron spectroscopy (XPS). The electrochemical characteristics of the modified alloy in Ringer's solution were determined. Anodisation results in a considerable increase in the corrosion resistance of the Ti-15Mo alloy. © 2013 Elsevier Ltd.

Author keywords

Ca and P incorporationCorrosion resistancePlasma electrolytic oxidationTi-15Mo alloyVanadium-free alloy

Indexed keywords

Engineering uncontrolled termsAlloy oxidationElectrochemical characteristicsEnergy dispersive x-ray spectroscopyLower voltagesOxidation processPlasma electrolytic oxidationRinger's solutionSample surface
Engineering controlled terms:AlloysAnodic oxidationCalciumCorrosion resistanceElectrolysisEnergy dispersive spectroscopyMolybdenum alloysPhosphorusPhotoelectronsPlasmasScanning electron microscopyX ray diffractionX ray photoelectron spectroscopy
Engineering main heading:Molybdenum

Funding details

Funding sponsor Funding number Acronym
Russian Foundation for Basic Research13-08-96007RFBR
Ural Branch, Russian Academy of Sciences12-Т-2-1009UB RAS

  • 1

    We acknowledge the support of the Ural Division of the Russian Academy of Sciences (Project 12-Т-2-1009) and the Russian Foundation for Basic Research (Project 13-08-96007).

  • ISSN: 00134686
  • CODEN: ELCAA
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/j.electacta.2013.02.102
  • Document Type: Article

  Simka, W.; Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, Poland;
© Copyright 2013 Elsevier B.V., All rights reserved.

Cited by 46 documents

Makurat-Kasprolewicz, B. , Ossowska, A.
Electrophoretically deposited titanium and its alloys in biomedical engineering: Recent progress and remaining challenges
(2024) Journal of Biomedical Materials Research - Part B Applied Biomaterials
Jauberteau, I. , Mayet, R. , Cornette, J.
Large Transfer of Nitrogen, Silicon and Titanium through Various Thin Mo–Ti/Si and Ti–Mo/Si Bilayer Films Processed in Expanding Microwave Plasma: Formation of Nitrides and Silicides
(2023) Coatings
Leśniak-Ziółkowska, K. , Brodacz, K. , Babilas, D.
Fungistatic and bacteriostatic Mg-enriched oxide coatings on titanium formed via plasma electrolytic oxidation
(2023) Applied Surface Science
View details of all 46 citations
Inform me when this document is cited in Scopus:
Set citation alert Set citation feed
{"topic":{"name":"Sodium Titanate; Bioactivity; Titanium Alloy (TiAl6V4)","id":1563,"uri":"Topic/1563","prominencePercentile":94.21191,"prominencePercentileString":"94.212","overallScholarlyOutput":0},"dig":"eb3fe329e83fb9e50cff3b8025088ad74f207ca1397af88ca5815bda93b0d6b3"}

SciVal Topic Prominence

Topic:
Prominence percentile: