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ZeolitesVolume 10, Issue 3, March 1990, Pages 169-173

Synthesis and characterization of the CoSAPO-14 and CoSAPO-34(Article)

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  • aBoris Kidrić Institute of Chemistry, Ljubljana
  • bFaculty of Technology and Metallurgy, University of Beograd, Beograd

Abstract

The hydrothermal synthesis of CoSAPO-14 and CoSAPO-34 in the presence of isopropylamine as the template is described. CoSAPO-14 is a new MeSAPO material that predominantly forms at 125°C, whereas CoSAPO-34 is the main product at 160°C. CoSAPO-14 has a triclinic and CoSAPO-34 has a trigonal unit cell. Both materials contain in their cavities a template that is hydrogen-bonded to the lattice. The synthesis in the presence of Co2+ ions is much more sensitive to the composition of the reaction gel than is usually found in the preparation of SAPO materials. © 1990.

Author keywords

cobalt(II) coordination geometryCoSAPO molecular sievesgel chemistryMolecular sieve synthesisorganic templatespectroscopy

Indexed keywords

Engineering controlled terms:Catalysts--AnalysisCobalt CompoundsColloidsPhosphates--X-ray Analysis
Engineering uncontrolled terms:Cobalt Coordination GeometryCollodial SolutionGel ChemistryIsopropylamineOrganic Template
Engineering main heading:Molecular Sieves

Funding details

  • 1

    This work was supported by the Research Community of" Slovenia and in part by the Research Fund of SR Srbia, Yugoslavia.

  • ISSN: 01442449
  • CODEN: ZEOLD
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/0144-2449(90)90041-O
  • Document Type: Article

  Rajić, N.; Boris Kidrić Institute of Chemistry,
© Copyright 2014 Elsevier B.V., All rights reserved.

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