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Organic GeochemistryVolume 16, Issue 1-3, 1990, Pages 621-629

Metal-organic matter interactions in the formation of an oil shale deposit(Article)

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  • aDepartment of Chemistry, Faculty of Science, University of Belgrade, P.O. Box 550, Yu-11001 Belgrade
  • bInstitute of Chemistry, Technology and Metallurgy, Njegoševa 12, Yu-11000 Belgrade

Abstract

An attempt was made to distinguish metal-organic matter interactions in two types of sulfate-reducing environments, mild (MR) and strong sulfate-reducing (SR), in the Aleksinac oil shale deposit (Oligocene-Miocene). Samples from the MR group show (all differences are statistically highly significant): lower organic matter content, compared with the SR group, higher O/C and N/C ratios (0.147 ± 0.054 and 0.041 ± 0.014, respectively, compared with 0.125 ± 0.031 and 0.035 ± 0.008, respectively, in the SR group), and higher Cu, Zn, Pb, Cr, Mo and Co contents than in the SR group. Statistically significant correlations between metals, the N/C and the SiO2/Al2O3 ratio in the MR group only, represent a record of highly interdependent processes of organic-metal-silicate interactions which had been occurring in the mild sulfate-reducing conditions during oil shale formation. © 1990.

Author keywords

Aleksinac oil shaleatomic O/C and N/C ratioearly diagenesismetal-organic interactionsSiO2/Al2O3 ratiosulfate-reducing conditions

Indexed keywords

Engineering controlled terms:Chemical AnalysisChemical Reactions--ReductionComputer SoftwareGeochemistry--Organic CompoundsMineralogy--Sulfates
Engineering uncontrolled terms:Aleksinac Oil ShaleEarly DiagenesisMetal-Organic Matter InteractionsSoftware Package STATGRAPHICSSulfate-Reducing Conditions
Engineering main heading:Oil Shale
GEOBASE Subject Index:diagenesismetal/organic interactionoil shalesulphate reducing environmentTertiary
Regional Index:Yugoslavia, Serbia, Aleksinac
  • ISSN: 01466380
  • CODEN: ORGED
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/0146-6380(90)90075-B
  • Document Type: Article

  Pfendt, P.A.; Department of Chemistry, Faculty of Science, University of Belgrade, P.O. Box 550,
© Copyright 2015 Elsevier B.V., All rights reserved.

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