Skip to main content
Microporous and Mesoporous MaterialsVolume 24, Issue 1-3, October 1998, Pages 83-87

A novel triclinically deformed chabazite-like aluminophosphate prepared in the presence of tris(1,2-diaminoethane)nickel(II) chloride(Article)

  Save all to author list
  • aNational Institute of Chemistry, Hajdrihova 19, 1000, Ljubljana, Slovenia
  • bFaculty of Technology and Metallurgy, University of Beograd, 11000, Beograd
  • cFac. of Chem. and Chem. Technology, University of, Ljubljana, Slovenia
  • dInst. of Chem. Phys. and Biophysics, Tallinn, Estonia

Abstract

The tris(1,2-diaminoethane)nickel(II) complex was found to be a novel structure-directing agent for the preparation of the chabazite-like AlPO4-34 molecular sieve. During crystallization the complex undergoes a ligand exchange, thus helping stabilization of the AlPO4's chabazite structure by hydroxyls that have exchanged one 1,2-diaminoethane (en) molecule from the Ni(II) coordination sphere. The exchanged complex, [Ni(en)2(OH)2], remains in the chabazite host causing a triclinic deformation of the rhombohedral chabazite framework. Upon calcination the triclinic phase completely transforms into the rhombohedral chabazite-like AlPO4-34 as evidenced from the in situ XRD pattern.

Author keywords

AlPO4-34Chabazite aluminophosphateMolecular sieveNi(II) complexTriclinic precursor

Indexed keywords

Engineering controlled terms:AgentsAluminum compoundsCalcinationCrystal structureCrystallizationDeformationNickel compoundsPhase transitionsX ray crystallography
Engineering uncontrolled terms:Chabazite aluminophosphateTrisaminoethanenickel chloride
Engineering main heading:Molecular sieves

Funding details

Funding sponsor Funding number Acronym
Eesti Teadusfondi2302ETF
Eesti TeadusfondiETF

  • 1

    P. Sarv acknowledges support from the Estonian Science Foundation under grant no. 2302.

  • ISSN: 13871811
  • CODEN: MIMMF
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/S1387-1811(98)00146-2
  • Document Type: Article
  • Publisher: Elsevier

  Rajic, N.; National Institute of Chemistry, Hajdrihova 19, 1000, Slovenia
© Copyright 2018 Elsevier B.V., All rights reserved.

Cited by 13 documents

Lyu, Y. , Yu, Z. , Yang, Y.
Metal-acid balance in the in-situ solid synthesized Ni/SAPO-11 catalyst for n-hexane hydroisomerization
(2019) Fuel
Komura, K. , Horibe, Y. , Yajima, H.
Synthesis, crystal structure and characterization of novel open framework CHA-type aluminophosphate involving a chiral diamine
(2016) Dalton Transactions
Lorena Picone, A. , Warrender, S.J. , Slawin, A.M.Z.
A co-templating route to the synthesis of Cu SAPO STA-7, giving an active catalyst for the selective catalytic reduction of NO
(2011) Microporous and Mesoporous Materials
View details of all 13 citations
Inform me when this document is cited in Scopus:
Set citation alert Set citation feed
{"topic":{"name":"Crystal Structure; Hydrothermal Method; Aluminophosphates","id":5210,"uri":"Topic/5210","prominencePercentile":54.26122,"prominencePercentileString":"54.261","overallScholarlyOutput":0},"dig":"4abdf8b71585bbfdb30b0273606a1eea00c96267bfba43a32a4a89f59b59634c"}

SciVal Topic Prominence

Topic:
Prominence percentile: