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Acta Crystallographica Section C: Crystal Structure CommunicationsVolume 58, Issue 5, May 2002, Pages m275-m279

Comparison of two polymeric transition metal complexes with 1, 4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)]·H2O(Article)

  • Karanović, L.,
  • Poleti, D.,
  • Rogan, J.,
  • Bogdanović, G.A.,
  • Spasojević-de Biré, A.
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  • aLaboratory of Crystallography, Faculty of Mining and Geology, Djušina 7, 11000 Belgrade
  • bLaboratory of Crystallography, Faculty of Mining and Geology, Djušina 7, 11000 Belgrade

Abstract

The two polymeric transition metal complexes with 1, 4-benzenedicarboxylate ions as bridging ligands were compared. The structures of the complexes were analyzed using low-temperature data collected at 193.2 K. The two complexes were in the form of zigzag chains. The Co ion was five coordinate with a distorted trigonal-bipyramidal geometry in the first compound. The Cu ion in the second complex was in a distorted octahedral 4+2 environment.

Indexed keywords

Engineering controlled terms:Atomic physicsChemical bondsCobalt compoundsComplexationCopper compoundsCrystal structureData acquisitionHydrogenParamagnetismParameter estimationThermal effects
Engineering uncontrolled terms:Ligands
Engineering main heading:Metallorganic polymers
  • ISSN: 01082701
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1107/S0108270102004341
  • Document Type: Article


© Copyright 2016 Elsevier B.V., All rights reserved.

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