Skip to main content
Journal of the Serbian Chemical SocietyVolume 62, Issue 7, 1997, Pages 615-618

Thermochemical behavior of C60. Kinetics of decomposition in different atmospheres(Article)

  Save all to author list
  • Faculty of Physical Chemistry, University of Belgrade, P.O. Box 137, YU-11001 Belgrade, Serbia

Abstract

The processes of decomposition of C60 in different atmospheres were investigated by TG and DTG methods. It was observed that the temperature maxima on the DTG curves are shifted towards higher temperatures by about 200 K in an inert nitrogen atmosphere compared to the values in air. Kinetic parameters were calculated by methods evaluated for processes under nonisothermal conditions. In air, where oxidation takes place, the values of the activation energy depending on the method used, are: Ea =145 ± 6 kJ/mol (Freeman-Carroll), Ea= 138 ± 16 kJ/mol (Ozawa), Ea = 121 ± 14 kJ/mol (Kissinger). In nitrogen, where sublimation occurs, the values of the activation energy are: Ea = 130 ± 8 kJ/mol (Freeman-Carroll). Ea =157 ± 16 kJ/mol (Ozawa), Ea = 141 ± 14 kJ/mol (Kissinger).

Author keywords

C60DeompositionFullerenesKinetics
  • ISSN: 03525139
  • CODEN: JSCSE
  • Source Type: Journal
  • Original language: English
  • Document Type: Article
  • Publisher: Serbian Chemical Society

  Simić, S.M.; Faculty of Physical Chemistry, University of Belgrade, P.O. Box 137, Serbia
© Copyright 2021 Elsevier B.V., All rights reserved.

Cited by 0 documents

{"topic":{"name":"Fullerene; Photoluminescence; X-Ray Diffraction","id":18080,"uri":"Topic/18080","prominencePercentile":13.540073,"prominencePercentileString":"13.540","overallScholarlyOutput":0},"dig":"70a95c7d8f77e72e0c0b3794324720f3f7c01c803201596820249f48cefec096"}

SciVal Topic Prominence

Topic:
Prominence percentile: