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Acta Crystallographica Section E: Structure Reports OnlineVolume 61, Issue 7, 1 July 2005, Pages m1354-m1356

(C4H12N2)[Zn2(PO 4)(HPO4)(H2PO4)], a layered zinc phosphate with intercalated N-methylpropane-1,3-diaminium cations(Article)(Open Access)

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  • aNational Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia
  • bFaculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Beograd, Yugoslavia
  • cFaculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, 1000 Ljubljana, Slovenia

Abstract

The title compound, catena-poly[[N-methylpropane-1,3-diaminium [μ-phosphato-(μ-hydrogen phosphato)(μ-dihydrogen phosphato) dizincate(II)]], {(C4H14N2)[Zn 2(PO4)(H-PO4)(H2PO 4)]}n, consists of macroanionic [Zn2(PO 4)(HPO4)-(H2PO4)]2- layers and intercalated (C4H12N2)2- cations. The layers are built up from ZnO4 and PO4/ HPO4/H2PO4 tetrahedra that result in small channels of approximate diameter 3.7 Å within the layers. Framework-to-framework O-H⋯O and template-to-framework N-H⋯O hydrogen bonds are important in stabilizing the structure. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.

  • ISSN: 16005368
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1107/S1600536805018908
  • Document Type: Article

  Logar, N.Z.; National Institute of Chemistry, Hajdrihova 19, Slovenia;
© Copyright 2008 Elsevier B.V., All rights reserved.

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