Skip to main content
Surface ScienceVolume 601, Issue 13, 1 July 2007, Pages 2868-2872

Raman scattering of the MoS2 and WS2 single nanotubes(Article)

  Save all to author list
  • aJožef Stefan Institute, Jamova 39, SI-1000 Ljubljana, Slovenia
  • bFaculty of Physics, University of Belgrade, POB 368, Belgrade, 11001, Serbia

Abstract

We report here the results of the first resonance Raman study on single MoS2 and WS2 nanotubes and microtubes synthesized by chemical transport reaction. These multiwall tubes represent the longest known inorganic nanotubes grown up to several millimetre lengths with diameters ranging from less than ten nanometers to several micrometers. The nanotubes grown at nearly equilibrium conditions contain extremely low density of structural defects. The selected area diffraction on the thick-wall nanotubes revealing the rhombohedral (3R) stacking, otherwise stable at elevated pressure above 4 GPa, provides indirect evidence of the presence of strain incorporated into the nanotube wall. Results are compared with phonon spectra of plate-like crystals of the same compound. The observed up-shift of Raman peaks in the tubes spectra is explained by the presence of strain. Well preserved crystal structure of tubes is confirmed by comparison with phonon spectra of nanostructured materials from literature. © 2006 Elsevier B.V. All rights reserved.

Author keywords

Lattice strainMolybdenum disulphideNanotubesRaman scatteringTungsten disulphide

Indexed keywords

Engineering controlled terms:Crystal structureMolybdenum compoundsPhononsRaman scatteringSynthesis (chemical)Tungsten compounds
Engineering uncontrolled termsChemical transport reactionLattice strainMolybdenum disulphideTungsten disulphide
Engineering main heading:Nanotubes
  • ISSN: 00396028
  • CODEN: SUSCA
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/j.susc.2006.12.050
  • Document Type: Article
  • Publisher: Elsevier

  Viršek, M.; Jožef Stefan Institute, Jamova 39, Slovenia;
© Copyright 2025 Elsevier B.V., All rights reserved.

Cited by 118 documents

Drnovšek, A. , Vengust, D. , Šumandl, P.
Facile Synthesis Route for Bulk Production of Complex Fullerene-Like MoS2 Nanostructures With Enhanced Tribological Properties
(2025) ChemPlusChem
Zhu, Q. , Li, W. , Hu, X.
High performance potassium/sodium-ion storage enabled by anchoring cobalt atoms on sulfur vacancies in WS2 nanosheets
(2024) Colloids and Surfaces A: Physicochemical and Engineering Aspects
Li, G. , Zhang, X. , Wang, Y.
A type-I van der Waals heterostructure formed by monolayer WS2 and trilayer PdSe2
(2024) Nanoscale
View details of all 118 citations
{"topic":{"name":"Nanotube; Fullerene; Molybdenum","id":14264,"uri":"Topic/14264","prominencePercentile":81.68664,"prominencePercentileString":"81.687","overallScholarlyOutput":0},"dig":"2e37c1abef424102631f0abef9f1a8b4d5f4a2ef84f051c11546ca402a330309"}

SciVal Topic Prominence

Topic:
Prominence percentile: