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Science of the Total EnvironmentVolume 389, Issue 2-3, 25 January 2008, Pages 235-244

A comparison of sediment quality results with acid volatile sulfide (AVS) and simultaneously extracted metals (SEM) ratio in Vojvodina (Serbia) sediments(Article)

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  • aFaculty of Technical Sciences, University of Novi Sad, Trg Dositeja Obradovica 6, 21000 Novi Sad, Serbia
  • bDepartment of Chemistry, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovica 3, 21000 Novi Sad, Serbia

Abstract

The acid-volatile sulfide (AVS), simultaneously extracted metals (SEM), total metals, and pore-water metal concentrations were studied in Vojvodina (Serbia) sediments. In Serbia, there are no regulations concerning sediment quality standards and sediment management. Harmonization of legislation in the domain of environmental protection with EU requirements will increase the significance of the sediment issue. Sediment quality was assessed according to Dutch standards, but the results were also compared with Canadian and USEPA (United States Environmental Protection Agency) guidelines for sediment quality. A comparison of the results based on different criteria for sediment quality assessment shows that they are sometimes contradictory. Therefore, a single approach to quality assessment may be insufficient. The Σ[SEM] / [AVS] ratio was found to be greater than one at several locations that were already recognized as places of high risk based on Dutch standards. Some other samples had Σ[SEM] / [AVS] < 1, despite of the high risk classification based on the Dutch evaluation. However, not all sediments with Σ[SEM] / [AVS] > 1 can cause increased toxicity because there are many other metal-binding phases in sediments. Metals that are associated with AVS may be released within sediments through storms, dredging activities, oxidation, etc., and may have adverse environmental impacts. This has to be taken into account during dredging, which is for some sediments necessary because the sediment is of class 4 (Dutch evaluation), because the dredging process will certainly increase the concentration of bioavailable heavy metals and disturb the sedimentation dynamics. The obtained results will be invaluable for future activities regarding dredging and sediment management in the country. © 2007 Elsevier B.V. All rights reserved.

Author keywords

ContaminationDredgingMetalsSediment

Indexed keywords

Engineering controlled terms:ContaminationDredgingExtractionLaws and legislation
Engineering uncontrolled terms:Acid volatile sulfidesSediment managementSediment qualitiesSimultaneously extracted metals
Engineering main heading:Sediments
EMTREE drug terms:metalsulfidevolatile agent
GEOBASE Subject Index:bioavailabilitycomparative studyconcentration (composition)dredgingenvironmental impactenvironmental protectionEuropean Unionlegislationporewatersediment analysistoxicity
EMTREE medical terms:articlebioavailabilityclassificationdredgingenvironmental impactenvironmental managementenvironmental protectionextractionhealth hazardlawmetal bindingoxidationpollution monitoringpriority journalquality controlsedimentstandardtoxicityYugoslavia
MeSH:AcidsEnvironmental MonitoringEnvironmental PollutantsGeologic SedimentsMetals, HeavySeasonsSolubilitySulfidesVolatilizationWater Pollutants, ChemicalYugoslavia
Regional Index:EurasiaEuropeSerbiaSouthern EuropeVojvodina

Chemicals and CAS Registry Numbers:

sulfide, 18496-25-8;

Acids; Environmental Pollutants; Metals, Heavy; Sulfides; Water Pollutants, Chemical

Funding details

Funding sponsor Funding number Acronym
Ministry of Science and Environmental ProtectionTR 6867B
  • 1

    The authors acknowledge the financial support of the Ministry of Science and Environmental Protection of the Republic of Serbia, in the frame of projects No. TR 6867B and No. ON 142058.

  • ISSN: 00489697
  • CODEN: STEVA
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/j.scitotenv.2007.09.006
  • PubMed ID: 17936333
  • Document Type: Article

  Prica, M.; Faculty of Technical Sciences, University of Novi Sad, Trg Dositeja Obradovica 6, Serbia;
© Copyright 2008 Elsevier B.V., All rights reserved. © MEDLINE® is the source for the MeSH terms of this document.

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