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IntermetallicsVolume 16, Issue 1, January 2008, Pages 107-112

Experimental study and thermodynamic calculation of Bi-Cu-Sb system phase equilibria(Article)

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  • aUniversity of Belgrade, Technical Faculty, VJ 12, 19210 Bor, Serbia
  • bUniversity of Pristina, Faculty of Technical Science, 38220 Kosovska Mitrovica, Serbia
  • cUniversity of Novi Sad, Faculty of Technical Sciences, Trg D. Obradovića 6, 21000 Novi Sad, Serbia

Abstract

Phase equilibria in the Bi-Cu-Sb ternary system have been studied experimentally and calculated by the CALPHAD method. Three calculated vertical sections from bismuth corner with molar ratio of copper and antimony equal to 7/3, 1/1 and 3/7 and one vertical section from antimony corner with molar ratio of copper and bismuth equal to 1/1 were compared with the DTA results from this work. Calculated isothermal section at 400 °C was compared with the results of SEM/EDX analysis from the present study. Reasonable agreement between calculations and experimental data was observed in all cases. © 2007 Elsevier Ltd. All rights reserved.

Author keywords

A. Ternary alloy systemsB. Phase diagramsE. Phase diagram, prediction

Indexed keywords

Engineering controlled terms:Bismuth compoundsEnergy dispersive spectroscopyPhase diagramsPhase equilibriaScanning electron microscopyThermodynamics
Engineering uncontrolled terms:CALPHAD methodMolar ratioPhase diagram, prediction
Engineering main heading:Ternary alloys

Funding details

Funding sponsor Funding number Acronym
Ministry of Science and Environmental Protection142043

  • 1

    The authors are grateful to Dr. Jan Vřešťál (Masaryk University Brno, Czech Republic) and Dr. Iwao Katayama (Department of Materials Science and Processing, Faculty of Engineering, Osaka University, Japan) for their help during the preparation of the paper. This work was supported by Ministry of Science and Environmental Protection of the Republic of Serbia (Project No. 142043). Calculations were performed by THERMOCALC software. This work was performed in the frame of the European action COST 531 on lead-free solder materials.

  • ISSN: 09669795
  • CODEN: IERME
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/j.intermet.2007.08.005
  • Document Type: Article

  Manasijević, D.; University of Belgrade, Technical Faculty, VJ 12, Serbia;
© Copyright 2008 Elsevier B.V., All rights reserved.

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