Skip to main content
ElectroanalysisVolume 5, Issue 8, September 1993, Pages 703-707

Application of glassy carbon substrated cyanide‐sensitive electrodes in determination of cyanide and mercaptan levels of wastewater(Article)

  Save all to author list
  • aFaculty of Technology and Metallurgy, Department of Analytical Chemistry, University of Belgrade, Karnegijeva 4, P.O. Box 494, Belgrade, YU 11001
  • bICTM Institute of Electrochemistry, University of Belgrade, Belgrade, YU 11001
  • cFaculty of Metallurgy, University of V. Vlahović, Titgrad, YU-81000

Abstract

Quantities of free and complex cyanides and mercaptans were determined in wastewater. Levels of free and complex cyanides were determined after previous oxidation of mercaptans by hydrogen peroxide. The procedure used for cyanide determination relied on applying a laboratory‐made glassy carbon (GC) substrated melt‐coated Agl “cyanide‐sensitive” electrode. The level of mercaptans was determined by iodometric titration in bicarbonate solution. Iodine was coulometrically generated using the depolarization end point detection on a GC/saturated calomel electrode indicating a couple connected directly to the recorder. Copyright © 1993 VCH Publishers, Inc.

Author keywords

CyanideGlassy CarbonWastewater
  • ISSN: 10400397
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1002/elan.1140050813
  • Document Type: Article

  Stankovic, S.M.; Faculty of Technology and Metallurgy, Department of Analytical Chemistry, University of Belgrade, Karnegijeva 4, P.O. Box 494,
© Copyright 2016 Elsevier B.V., All rights reserved.

Cited by 4 documents

Mazumder, A. , Kumar, A. , Dubey, D.K.
High resolution 19F{1H} nuclear magnetic resonance spectroscopy and liquid chromatography-solid phase extraction-offline 1H nuclear magnetic resonance spectroscopy for conclusive detection and identification of cyanide in water samples
(2013) Journal of Chromatography A
Christison, T.T. , Rohrer, J.S.
Direct determination of free cyanide in drinking water by ion chromatography with pulsed amperometric detection
(2007) Journal of Chromatography A
Velasco-Arjona, A. , Luque De Castro, M.D.
A robotics-potentiometric method for the determination of mercaptan sulfur in fuels
(1999) Fresenius' Journal of Analytical Chemistry
View details of all 4 citations

SciVal Topic Prominence

Topic:
Prominence percentile: