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Bulletin des Sociétés Chimiques BelgesVolume 102, Issue 8, 1993, Pages 539-544

Crystal Structure and Solid State Conformation of 5‐Hydroxy‐8,9‐Dioxo‐8,9‐Seco‐α‐Cholestan‐3β‐yl Acetate(Article)

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  • aLaboratoire de Chimie Physique Et de Cristallographie, Université Catholique de Louvain, 1 Place Louis Pasteur, Louvain-La-Neuve, B-1348, Belgium
  • bFaculty of Chemistry, University of Belgrade, Institute of Chemistry, Studentski trg 16, P.O. Box 550, Belgrade, YU‐11001

Abstract

The molecular structure of the title compound, which might be a possible intermediate in the synthesis of 5,10:8,9‐diseco‐steroids (=steroklastanes), was determined by X‐ray analysis. Hydrogen bonding between the 5α‐hydroxyl group and the 9‐oxo function attached to the ten‐membered ring, and the presence of two conformational forms of the side‐chain in the solid state structure of 2 are established. Copyright © 1993 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim

  • ISSN: 00379646
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1002/bscb.19931020806
  • Document Type: Article

  Tinant, B.; Laboratoire de Chimie Physique Et de Cristallographie, Université Catholique de Louvain, 1 Place Louis Pasteur, Belgium
© Copyright 2016 Elsevier B.V., All rights reserved.

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