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Energy Conversion and ManagementVolume 168, 15 July 2018, Pages 494-504

Continuous biodiesel production under subcritical condition of methanol – Design of pilot plant and packed bed reactor with MnCO3/Na-silicate catalyst(Article)(Open Access)

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  • aState Key Laboratory of Biogeology and Environmental Geology and School of Environmental Studies, China University of Geosciences, Wuhan, 430074, China
  • bUniversity of Belgrade, Faculty of Technology and Metallurgy, Karnegijeva 4, Belgrade, 11000, Serbia
  • cUniversity of Niš, Faculty of Technology, Bulevar oslobodjenja 124, Leskovac, 16000, Serbia
  • dInstitute of Technical Sciences of the Serbian Academy of Sciences and Arts, Knez Mihailova 35, Belgrade, 11000, Serbia

Abstract

The continuous biodiesel production from soybean oil was carried out under the subcritical condition of methanol with MnCO3/Na-silicate as a heterogeneous catalyst. The transesterification rate was first investigated in a set of experiments performed in a batch autoclave at 448 K using methanol-to-oil molar ratio of 18:1 and various catalyst loadings (5, 10 and 20 wt% based on the oil mass). The results from these experiments, as well as the experimental data and the appropriate kinetic model recently reported in the literature were used for designing a packed bed tubular reactor (PBTR), a main unit of the pilot plant with the capacity of 100 L of biodiesel per day. The pilot plant was constructed and tested under various operating conditions. The first 11 h of the pilot-plant operation was realized in the tubular reactor packed with inert glass beads (i.e. without the catalyst) in order to analyze the effect of the non-catalyzed subcritical biodiesel (fatty acid methyl esters, FAME) production. Then, glass beads were replaced with a mix of MnCO3/Na-silicate catalyst particles and glass beads, and the catalytic biodiesel production was continuously run under the subcritical methanol condition for 85 h. Two mass balance tests during the continuous pilot plant operation were performed. © 2018 Elsevier Ltd

Author keywords

BiodieselKinetic modelingMnCO3/Na-silicate catalystPilot-plant designSubcritical methanolysis

Indexed keywords

Engineering controlled terms:BiodieselCatalystsGlassGranular materialsKinetic theoryManganese compoundsMethanolPacked bedsPilot plantsSoybean oil
Engineering uncontrolled termsContinuous pilot plantsFatty acid methyl esterHeterogeneous catalystKinetic modelingMethanolysisPacked-bed tubular reactorsPilot plant operationsPlant designs
Engineering main heading:Fatty acids

Funding details

Funding sponsor Funding number Acronym
Ministarstvo Prosvete, Nauke i Tehnološkog RazvojaMPNTR
International Science and Technology Cooperation Programme2013DFG92250,45001ISTCP
International Science and Technology Cooperation ProgrammeISTCP
  • 1

    This study was supported by the International S&T Cooperation Program of China (Grant No. 2013DFG92250 ) as well as the research Grant No. 45001 of the Ministry of Education, Science and Technological Development of the Republic of Serbia .

  • ISSN: 01968904
  • CODEN: ECMAD
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/j.enconman.2018.05.028
  • Document Type: Article
  • Publisher: Elsevier Ltd

  Liu, H.; State Key Laboratory of Biogeology and Environmental Geology and School of Environmental Studies, China University of Geosciences, Wuhan, China;
© Copyright 2018 Elsevier B.V., All rights reserved.

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