Catena-[bis(o-aminobenzoato-κ3 N,O:O′)Mn(II)](Article)(Open Access)
- aChemistry Department, Faculty of Science, Tripoli University, Tripoli, State of Libya
- bDepartment of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, Karnegijeva 4, Belgrade, 11000, Serbia
Abstract
In the title complex, [C14H12MnN2O4]n the Mn(II) cation octahedrally coordinated by two N and two O atoms from two o-aminobenzoate ligands and two O atoms from another two o-aminobenzoate ligands. The carboxylate groups of two o-aminobenzoate anions coordinate to the Mn(II) cation in a monodentate manner, whereas the other two o-aminobenzoate anions chelate the Mn(II) cations through the O-atom of the carboxylate group and the N-atom of the amino group. This complex adopts the syn-anti carboxylate bridging mode with the conformation syn(eq)-anti(eq). The title complex is a two-dimensional coordination polymer based on an infinite Mn–O–C–O–Mn chain. There is hydrogen bond interaction within the two dimensional network. The adjacent two-dimensional network is packed only by Van der Waals interactions. © 2015 King Saud University
Indexed keywords
| Engineering controlled terms: | AtomsCarboxylationComplex networksCrystal structureHydrogen bondsIndium compoundsLigandsPositive ionsVan der Waals forces |
|---|---|
| Engineering uncontrolled terms | 2-aminobenzoic acidCarboxylateCarboxylate groupsHydrogen bond interactionOctahedralOctahedrally coordinatedTwo-dimensional networksVan Der Waals interactions |
| Engineering main heading: | Manganese compounds |
- ISSN: 18785352
- Source Type: Journal
- Original language: English
- DOI: 10.1016/j.arabjc.2015.04.012
- Document Type: Article
- Publisher: Elsevier B.V.
El-Mehdawi, R.M.; Chemistry Department, Faculty of Science, Tripoli University, Tripoli, State of Libya;
© Copyright 2018 Elsevier B.V., All rights reserved.