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Physica Status Solidi (B) Basic ResearchVolume 255, Issue 12, December 2018, Article number 1800196

Rigid-Unit Modes in Layers and Nanotubes(Article)

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  • NanoLab, Center for Quantum Theoretical Physics, Faculty of Physics, University of Belgrade, Belgrade, 11158, Serbia

Abstract

Among the vibrational modes of a complex system, apart from the rigid-body displacements of the system as a whole, there can exist also the rigid-body displacements of the subsystems. While in the standard considerations of the layered structures, it is understood that rigid-layer modes emerge due to the relatively weaker inter-layer (than intra-layer) coupling, here we derive universal dynamical condition which provides exactly rigid modes of subsystems. It clarifies that weak inter-layer interaction itself is sufficient to induce the layer modes which are only approximately rigid. The obtained exact condition separates effective dynamical matrix, which in the layered systems corresponds to the well-known linear chain model. The analysis of quasi-one-dimensional systems is more refined, due to additional rigid-body degrees of freedom: the twisting modes and their interference with other modes (e.g., mixing of twisting and breathing modes in multiwalled nanotubes). It is also shown that condition for exactly rigid modes of subsystems can be fulfilled due to symmetry, used also to determine infrared and Raman activity of rigid-layer modes in uniform multilayers (with one repeated monolayer). © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Author keywords

layered materialslinear chain modelnanotubesnormal modesrigid-layer modes

Indexed keywords

Engineering controlled terms:Degrees of freedom (mechanics)Rigid structures
Engineering uncontrolled termsInterlayer interactionsLayered materialLinear chainMulti-walled nanotubesNormal modesQuasi-one-dimensional systemsRigid body displacementRigid-layer modes
Engineering main heading:Nanotubes

Funding details

Funding sponsor Funding number Acronym
Ministarstvo Prosvete, Nauke i Tehnološkog RazvojaON171035,SANU-F-93MPNTR
  • 1

    This research was funded by Serbian Ministry of Science (Projects ON171035 and SANU-F-93).

  • ISSN: 03701972
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1002/pssb.201800196
  • Document Type: Article
  • Publisher: Wiley-VCH Verlag

  Milošević, I.; NanoLab, Center for Quantum Theoretical Physics, Faculty of Physics, University of Belgrade, Belgrade, Serbia;
© Copyright 2020 Elsevier B.V., All rights reserved.

Cited by 2 documents

Pizzi, G. , Milana, S. , Ferrari, A.C.
Shear and Breathing Modes of Layered Materials
(2021) ACS Nano
Popović, Z.P. , Nikolić, B. , Milošević, I.
Symmetry of rigid-layer modes: Raman and infrared activity
(2019) Physica E: Low-Dimensional Systems and Nanostructures
View details of all 2 citations
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