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Physica E: Low-Dimensional Systems and NanostructuresVolume 114, October 2019, Article number 113613

Symmetry of rigid-layer modes: Raman and infrared activity(Article)

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  • NanoLab, QTP Center, Faculty of Physics, University of Belgrade, Studentski trg 12, Belgrade, 11158, Serbia

Abstract

Symmetry of multilayer structures is analyzed in order to count and specify Raman and infrared active rigid-layer vibrational modes. Effective Hessian matrix of rigid-layer dynamics corresponds to simple model of linear chain (composed of monolayers); its symmetry, derived from the symmetry of the multilayer, assigns the modes and determines their activity. These general results are illustrated on currently most studied (multi)layered structures: graphene, transition metal dichacogenides, phosphorene, boron nitride and graphene based materials. © 2019 Elsevier B.V.

Author keywords

GrapheneLayered structuresRaman activityRigid-layer modesSymmetry of layersTransition metal dichacogenides

Indexed keywords

Engineering controlled terms:III-V semiconductorsMultilayersTransition metals
Engineering uncontrolled termsHessian matricesInfrared activityLayered StructuresMultilayer structuresRaman activitiesRigid-layer modesSimple modelingVibrational modes
Engineering main heading:Graphene

Funding details

Funding sponsor Funding number Acronym
Ministarstvo Prosvete, Nauke i Tehnološkog RazvojaON171035,SANU-F-93MPNTR

  • 1

    This research is funded by Serbian Ministry of Science (Projects ON171035 and SANU-F-93 ).

  • ISSN: 13869477
  • CODEN: PELNF
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1016/j.physe.2019.113613
  • Document Type: Article
  • Publisher: Elsevier B.V.

  Nikolić, B.; NanoLab, QTP Center, Faculty of Physics, University of Belgrade, Studentski trg 12, Belgrade, Serbia;
© Copyright 2019 Elsevier B.V., All rights reserved.

Cited by 3 documents

Poulos, M. , Papagelis, K. , Koukaras, E.N.
Temperature dependence of phonon energies and lifetimes in single- and few-layered graphene
(2024) Physical Review B
Nikolić, B. , Milošević, I. , Vuković, T.
Irreducible and site-symmetry-induced representations of single/double ordinary/grey layer groups
(2022) Acta Crystallographica Section A: Foundations and Advances
Pizzi, G. , Milana, S. , Ferrari, A.C.
Shear and Breathing Modes of Layered Materials
(2021) ACS Nano
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