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MicromachinesVolume 11, Issue 9, September 2020, Article number 818

Monolithically integrated diffused silicon two-zone heaters for silicon-pyrex glass microreactors for production of nanoparticles: Heat exchange aspects(Article)(Open Access)

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  • aCenter of Microelectronic Technologies, Institute of Chemistry, Technology and Metallurgy-National Institute of the Republic of Serbia, University of Belgrade, Njegoševa 12, Belgrade, 11000, Serbia
  • bFaculty of Physical Chemistry, University of Belgrade, Studentski trg 12-16, Beograd, 11000, Serbia

Abstract

We present the design, simulation, fabrication and characterization of monolithically integrated high resistivity p-type boron-diffused silicon two-zone heaters in a model high temperature microreactor intended for nanoparticle fabrication. We used a finite element method for simulations of the heaters' operation and performance. Our experimental model reactor structure consisted of a silicon wafer anodically bonded to a Pyrex glass wafer with an isotropically etched serpentine microchannels network. We fabricated two separate spiral heaters with different temperatures, mutually thermally isolated by barrier apertures etched throughout the silicon wafer. The heaters were characterized by electric measurements and by infrared thermal vision. The obtained results show that our proposed procedure for the heater fabrication is robust, stable and controllable, with a decreased sensitivity to random variations of fabrication process parameters. Compared to metallic or polysilicon heaters typically integrated into microreactors, our approach offers improved control over heater characteristics through adjustment of the Boron doping level and profile. Our microreactor is intended to produce titanium dioxide nanoparticles, but it could be also used to fabricate nanoparticles in different materials as well, with various parameters and geometries. Our method can be generally applied to other high-temperature microsystems. © 2020 by the authors.

Author keywords

DiffionHigh-temperature microreactorsIntegrated heaterNanoparticle synthesisPyrex glass micromachiningSilicon micromachiningThermal visionTitaniaTitanium dioxide

Indexed keywords

Engineering controlled terms:BoronChemical reactorsFabricationGlassGlass industryMonolithic integrated circuitsNanoparticlesSensitivity analysisSerpentineTiO2 nanoparticlesTitanium dioxideWafer bonding
Engineering uncontrolled termsExperimental modelingFabrication and characterizationsFabrication processImproved controlsMonolithically integratedRandom variationReactor structuresSerpentine microchannels
Engineering main heading:Silicon wafers

Funding details

Funding sponsor Funding number Acronym
Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja200026,451-03-68/2020-14/200026MPNTR
  • 1

    Funding: This work was partially funded by the Ministry of Education, Science and Technological Development of the Republic of Serbia, grant number 451-03-68/2020-14/200026.

  • ISSN: 2072666X
  • Source Type: Journal
  • Original language: English
  • DOI: 10.3390/mi11090818
  • Document Type: Article
  • Publisher: MDPI AG

  Rafajilović, M.R.; Center of Microelectronic Technologies, Institute of Chemistry, Technology and Metallurgy-National Institute of the Republic of Serbia, University of Belgrade, Njegoševa 12, Belgrade, Serbia;
© Copyright 2020 Elsevier B.V., All rights reserved.

Cited by 4 documents

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Design of a Microfluidic Photocatalytic Reactor for Removal of Volatile Organic Components: Process Simulation and Techno-Economic Assessment
(2022) ACS Omega
Ivanov, A.
Editorial for the special issue on micro-manufacturing and applications
(2021) Micromachines
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