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RSC AdvancesVolume 11, Issue 26, 23 April 2021, Pages 15933-15942

All near-infrared multiparametric luminescence thermometry using Er3+, Yb3+-doped YAG nanoparticles(Article)(Open Access)

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  • aVinča Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, P.O. Box 522, Belgrade, 11001, Serbia
  • bInstitute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna 2, Wroclaw, 50-422, Poland

Abstract

This paper presents four new temperature readout approaches to luminescence nanothermometry in spectral regions of biological transparency demonstrated on Yb3+/Er3+-doped yttrium aluminum garnet nanoparticles. Under the 10 638 cm-1 excitation, down-shifting near infrared emissions (>10 000 cm-1) are identified as those originating from Yb3+ ions' 2F5/2 → 2F7/2 (∼9709 cm-1) and Er3+ ions' 4I13/2 → 4I15/2 (∼6494 cm-1) electronic transitions and used for 4 conceptually different luminescence thermometry approaches. Observed variations in luminescence parameters with temperature offered an exceptional base for studying multiparametric temperature readouts. These include the temperature-dependence of: (i) intensity ratio between emissions from Stark components of Er3+ 4I13/2 level; (ii) intensity ratio between emissions of Yb3+ (2F5/2 → 2F7/2 transition) and Er3+ (4I13/2 → 4I15/2 transition); (iii) band shift and bandwidth and (iv) lifetime of the Yb3+ emission (2F5/2 → 2F7/2 transition) with maximal sensitivities of 1% K-1, 0.8% K-1, 0.09 cm-1 K-1, 0.46% K-1 and 0.86% K-1, respectively. The multimodal temperature readout provided by this material enables its application in different luminescence thermometry setups as well as improved the reliability of the temperature sensing by the cross-validation between measurements. © 2021 The Royal Society of Chemistry.

Indexed keywords

Engineering controlled terms:LuminescenceNanoparticlesTemperature distributionThermometersYttrium aluminum garnet
Engineering uncontrolled termsCross validationElectronic transitionIntensity ratioITS applicationsNear-infrared emissionsTemperature dependenceTemperature readoutTemperature sensing
Engineering main heading:Infrared devices

Funding details

Funding sponsor Funding number Acronym
Horizon 2020 Framework Programme
See opportunities by H2020
801305H2020
Ministarstvo Prosvete, Nauke i Tehnološkog RazvojaMPNTR
  • 1

    This research was funded by the European Union's Horizon 2020 FET-Open project NanoTBtech (grant agreement No.: 801305). Authors from Serbia would like to acknowledge the funding from the Ministry of Education, Science and Technological Development of the Republic of Serbia.

  • ISSN: 20462069
  • CODEN: RSCAC
  • Source Type: Journal
  • Original language: English
  • DOI: 10.1039/d1ra01647d
  • Document Type: Article
  • Publisher: Royal Society of Chemistry

  Dramićanin, M.D.; Vinča Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, P.O. Box 522, Belgrade, Serbia;
© Copyright 2021 Elsevier B.V., All rights reserved.

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Advancing luminescence thermometry: Employing multiple fluorescence intensity ratios of YAG:Er3+/Mn4+ nanocrystals for supersensitive temperature sensing
(2025) Ceramics International
View details of all 20 citations
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