

This paper presents four new temperature readout approaches to luminescence nanothermometry in spectral regions of biological transparency demonstrated on Yb3+/Er3+-doped yttrium aluminum garnet nanoparticles. Under the 10 638 cm-1 excitation, down-shifting near infrared emissions (>10 000 cm-1) are identified as those originating from Yb3+ ions' 2F5/2 → 2F7/2 (∼9709 cm-1) and Er3+ ions' 4I13/2 → 4I15/2 (∼6494 cm-1) electronic transitions and used for 4 conceptually different luminescence thermometry approaches. Observed variations in luminescence parameters with temperature offered an exceptional base for studying multiparametric temperature readouts. These include the temperature-dependence of: (i) intensity ratio between emissions from Stark components of Er3+ 4I13/2 level; (ii) intensity ratio between emissions of Yb3+ (2F5/2 → 2F7/2 transition) and Er3+ (4I13/2 → 4I15/2 transition); (iii) band shift and bandwidth and (iv) lifetime of the Yb3+ emission (2F5/2 → 2F7/2 transition) with maximal sensitivities of 1% K-1, 0.8% K-1, 0.09 cm-1 K-1, 0.46% K-1 and 0.86% K-1, respectively. The multimodal temperature readout provided by this material enables its application in different luminescence thermometry setups as well as improved the reliability of the temperature sensing by the cross-validation between measurements. © 2021 The Royal Society of Chemistry.
| Engineering controlled terms: | LuminescenceNanoparticlesTemperature distributionThermometersYttrium aluminum garnet |
|---|---|
| Engineering uncontrolled terms | Cross validationElectronic transitionIntensity ratioITS applicationsNear-infrared emissionsTemperature dependenceTemperature readoutTemperature sensing |
| Engineering main heading: | Infrared devices |
| Funding sponsor | Funding number | Acronym |
|---|---|---|
| Horizon 2020 Framework Programme See opportunities by H2020 | 801305 | H2020 |
| Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja | MPNTR |
This research was funded by the European Union's Horizon 2020 FET-Open project NanoTBtech (grant agreement No.: 801305). Authors from Serbia would like to acknowledge the funding from the Ministry of Education, Science and Technological Development of the Republic of Serbia.
Dramićanin, M.D.; Vinča Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, P.O. Box 522, Belgrade, Serbia;
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