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Journal of the Serbian Chemical SocietyVolume 86, Issue 6, 29 June 2021, Pages 585-590

Influence of electrochemical conditions on the regio- And stereoselectivity of selenocyclization of alkenyl hydantoins(Article)(Open Access)

[УТИЦАЈ ЕЛЕКТРОХЕМИЈСКИХ УСЛОВА НА РЕГИО- И СТЕРЕОСЕЛЕКТИВНОСТ СЕЛЕНОЦИКЛИЗАЦИЈЕ АЛКЕНИЛХИДАНТОИНА]

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  • aInstitute for Information Technologies, University of Kragujevac, Jovana Cvijića bb, Kragujevac, Serbia
  • bFaculty of Science, University of Kragujevac, Radoja Domanovića 12, Kragujevac, Serbia

Abstract

5-Alkenyl hydantoins and alkenyl spirohydantoins are converted into bicyclic and tricyclic hydantoins, under indirect electrochemical conditions, generating the phenylselenyl cation in situ. The reactions proceeded in good to exelent yields. The influence of electrochemical conditions on regio- and diastereoselectivity of the selenocyclization reactions is investigated. © 2021 Serbian Chemical Society. All rights reserved.

Author keywords

Constant-current electrolysisElectrosynthesisRing closureSelenylation

Funding details

Funding sponsor Funding number Acronym
Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja451-03-9/2021-14MPNTR

  • 1

    Acknowledgement. This work was supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (Cont. No: 451-03-9/2021-14).

  • ISSN: 03525139
  • CODEN: JSCSE
  • Source Type: Journal
  • Original language: English
  • DOI: 10.2298/JSC201022023S
  • Document Type: Article
  • Publisher: Serbian Chemical Society

  Šmit, B.M.; Institute for Information Technologies, University of Kragujevac, Jovana Cvijića bb, Kragujevac, Serbia;
© Copyright 2021 Elsevier B.V., All rights reserved.

Cited by 2 documents

Qu, P. , Jiang, Y.-Q. , Wang, Y.-H.
Recent progress in the electrochemical selenofunctionalization of alkenes and alkynes
(2023) Green Chemistry
Šmit, B. , Stanić, P.B. , Janković, N.
Selenocyclization by Formation of Carbon-nitrogen Bonds
(2022) Current Organic Synthesis
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