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PolymersVolume 15, Issue 5, March 2023, Article number 1176

Natural Rubber Composites Using Hydrothermally Carbonized Hardwood Waste Biomass as a Partial Reinforcing Filler- Part I: Structure, Morphology, and Rheological Effects during Vulcanization(Article)(Open Access)

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  • aFaculty of Technology Novi Sad, University of Novi Sad, Bulevar cara Lazara 1, Novi Sad, 21000, Serbia
  • bInstitute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovskeho nam. 2, Praha, CZ-162 00, Czech Republic

Abstract

A new generation biomass-based filler for natural rubber, ‘hydrochar’ (HC), was obtained by hydrothermal carbonization of hardwood waste (sawdust). It was intended as a potential partial replacement for the traditional carbon black (CB) filler. The HC particles were found (TEM) to be much larger (and less regular) than CB: 0.5–3 µm vs. 30–60 nm, but the specific surface areas were relatively close to each other (HC: 21.4 m2/g vs. CB: 77.8 m2/g), indicating a considerable porosity of HC. The carbon content of HC was 71%, up from 46% in sawdust feed. FTIR and 13C-NMR analyses indicated that HC preserved its organic character, but it strongly differs from both lignin and cellulose. Experimental rubber nanocomposites were prepared, in which the content of the combined fillers was set at 50 phr (31 wt.%), while the HC/CB ratios were varied between 40/10 and 0/50. Morphology investigations proved a fairly even distribution of HC and CB, as well as the disappearance of bubbles after vulcanization. Vulcanization rheology tests demonstrated that the HC filler does not hinder the process, but it significantly influences vulcanization chemistry, canceling scorch time on one hand and slowing down the reaction on the other. Generally, the results suggest that rubber composites in which 10–20 phr of CB are replaced by HC might be promising materials. The use of HC in the rubber industry would represent a high-tonnage application for hardwood waste. © 2023 by the authors.

Author keywords

bio-sourced raw materialscarbon blackhydrocharhydrothermal carbonizationnatural rubber compositesvulcanization chemistry

Indexed keywords

Engineering controlled terms:CarbonizationFillersHardwoodsMorphologyRubberRubber applicationsRubber industryVulcanization
Engineering uncontrolled termsBio-sourced raw materialHydrocharHydrothermal carbonizationHydrothermallyNatural rubber compositesReinforcing fillersStructure effectVulcanisationVulcanization chemistryWaste biomass
Engineering main heading:Carbon black
PaperChem Variable:AnatomyCarbonizationFillersHardwoodsRubberVulcanization

Funding details

Funding sponsor Funding number Acronym
Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja200134,451-03-47/2023-01/200134,CA1911MPNTR
Technology Agency of the Czech RepublicTN02000020TACR
  • 1

    The authors would like to thank the Ministry of Education, Science and Technological Development of the Republic of Serbia, Project No. 451-03-47/2023-01/200134, the European Cooperation in Science and Technology (COST Action Essence CA1911), and the Technology Agency of the Czech Republic, grant number TN02000020, for their financial support.

  • ISSN: 20734360
  • Source Type: Journal
  • Original language: English
  • DOI: 10.3390/polym15051176
  • Document Type: Article
  • Publisher: MDPI

  Lubura, J.; Faculty of Technology Novi Sad, University of Novi Sad, Bulevar cara Lazara 1, Novi Sad, Serbia;
  Strachota, A.; Institute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovskeho nam. 2, Praha, Czech Republic;
© Copyright 2023 Elsevier B.V., All rights reserved.

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