

Natural rubber composites were reinforced by the co-fillers ‘hydrochar’ (HC), obtained by hydrothermal carbonization of hardwood sawdust and commercial carbon black (CB). The content of the combined fillers was kept constant while their ratio was varied. The aim was to test the suitability of HC as a partial filler in natural rubber. Due to its larger particle size and hence smaller specific surface area, large amounts of HC reduced the crosslinking density in the composites. On the other hand, due to its unsaturated organic character, HC was found to display interesting chemical effects: if it was used as the exclusive filler component, it displayed a very strong anti-oxidizing effect, which greatly stabilized the rubber composite against oxidative crosslinking (and hence embrittlement). HC also affected the vulcanization kinetics in different ways, depending on the HC/CB ratio. Composites with HC/CB ratios 20/30 and 10/40 displayed interesting chemical stabilization in combination with fairly good mechanical properties. The performed analyses included vulcanization kinetics, tensile properties, determination of density of permanent and reversible crosslinking in dry and swollen states, chemical stability tests including TGA, thermo-oxidative aging tests in air at 180 °C, simulated weathering in real use conditions (‘Florida test’), and thermo-mechanical analyses of degraded samples. Generally, the results indicate that HC could be a promising filler material due to its specific reactivity. © 2023 by the authors.
| Engineering controlled terms: | Carbon blackCarbonizationChemical stabilityCrosslinkingFillersHardwoodsParticle sizeParticle size analysisRubberVulcanization |
|---|---|
| Engineering uncontrolled terms | Bio-sourced raw materialDegradation stabilityHydrocharHydrothermal carbonizationHydrothermallyMechanical agingNatural rubber compositesReinforcing fillersVulcanization kineticsWaste biomass |
| Engineering main heading: | Degradation |
| Funding sponsor | Funding number | Acronym |
|---|---|---|
| Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja | 200134,451-03-47/2023-01/200134,CA1911 | MPNTR |
| Technology Agency of the Czech Republic | TN02000020 | TACR |
The authors would like to acknowledge the Ministry of Education, Science and Technological Development of the Republic of Serbia, Project No. 451-03-47/2023-01/200134, the European Cooperation in Science and Technology (COST Action Essence CA1911), and the Technology Agency of the Czech Republic, grant number TN02000020, for their financial support.
Lubura, J.; Faculty of Technology Novi Sad, University of Novi Sad, Bulevar cara Lazara 1, Bulevar cara Lazara 1, Novi Sad, Serbia;
Pavličević, J.; Faculty of Technology Novi Sad, University of Novi Sad, Bulevar cara Lazara 1, Novi Sad, Serbia;
Strachota, A.; Institute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovskeho nam. 2, Praha, Czech Republic;
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